Skip to content

Proceedings of the National Academy of Sciences

ISSN 0027-8424

37 papers in the library · 14,033 citations · publishing 1970-2026

Papers

Evolution of consciousness: Phylogeny, ontogeny, and emergence from general anesthesia

Proceedings of the National Academy of Sciences June 10, 2013 George A. Mashour, Michael T. Alkire 148 citations

Consciousness likely emerged early in vertebrate evolution, as the basic neural mechanisms supporting it are ancient and highly conserved across species. The stepwise emergence from general anesthesia can serve as a reproducible model to study consciousness across species. The neurobiological structure of the vertebrate central nervous system is evolutionarily ancient, and the neurophysiologic mechanisms supporting human consciousness are found at the earliest points of vertebrate brain evolution. Differences between species in the ability to experience the world are of degree, not kind, supporting Darwin's insight and the Cambridge Declaration on Consciousness in Non-Human Animals.

Lysergic acid diethylamide (LSD) promotes social behavior through mTORC1 in the excitatory neurotransmission

Proceedings of the National Academy of Sciences January 25, 2021 Danilo de Gregorio, Jelena Popić, Justine P. Enns et al. 137 citations

Repeated doses of LSD (30 μg/kg daily for 7 days) increase social behavior in male mice without producing antidepressant or anxiety-reducing effects. The prosocial effect requires the integrity of mTORC1 in excitatory glutamatergic neurons of the medial prefrontal cortex (mPFC), as shown by optogenetic inhibition and conditional knockout experiments. LSD potentiates AMPA and 5-HT2A synaptic responses in the mPFC and increases phosphorylation of Akt and mTOR, but does not affect NMDA or 5-HT1A responses. In mice lacking Raptor in GABAergic neurons, LSD still promotes social behavior. The findings suggest that 5-HT2A/AMPA/mTORC1 signaling in mPFC excitatory neurons mediates LSD's prosocial effects, offering a potential target for treating social deficits in autism and social anxiety.

Serotonin-Sensitive Adenylate Cyclase in Neural Tissue and Its Similarity to the Serotonin Receptor: A Possible Site of Action of Lysergic Acid Diethylamide

Proceedings of the National Academy of Sciences March 1, 1974 James A. Nathanson, Paul Greengard 95 citations

An enzyme called adenylate cyclase, found in the thoracic ganglia of an insect nervous system, is specifically activated by low concentrations of serotonin. This activation is selectively blocked by very low concentrations of D-lysergic acid diethylamide (LSD), 2-bromo-LSD, and cyproheptadine, substances known to block certain serotonin receptors in living organisms. The inhibition is competitive with respect to serotonin, and the inhibitory constant of LSD for this serotonin-sensitive adenylate cyclase is 5 nM. These findings suggest that the serotonin receptor in neural tissue is closely linked to this enzyme, which may mediate serotonergic neurotransmission, and that some physiological effects of LSD might occur through interaction with this enzyme.

Antagonism of histamine-activated adenylate cyclase in brain by D-lysergic acid diethylamide.

Proceedings of the National Academy of Sciences December 1, 1977 J P Green, C L Johnson, Harel Weinstein et al. 91 citations

D-Lysergic acid diethylamide (LSD) and D-2-bromolysergic acid diethylamide (BOL) act as competitive antagonists of histamine-activated adenylate cyclase in broken cell preparations from guinea pig hippocampus and cortex. The adenylate cyclase is linked to the histamine H2-receptor. Both compounds show structural similarity to potent H2-antagonists. BOL is 10 times more potent as an H2-antagonist than cimetidine, the most potent H2-antagonist previously reported, while LSD is about equipotent to cimetidine. Blockade of H2-receptors may contribute to the behavioral effects of these compounds.

Steric and Electronic Relationships among Some Hallucinogenic Compounds

Proceedings of the National Academy of Sciences September 1, 1970 Sungzong Kang, Jack Peter Green 64 citations

A common mechanism may underlie how structurally different hallucinogens—LSD, indolealkylamines, and methoxylated amphetamines—interact with their receptor. In LSD, the aromatic benzene ring A and the N-6 nitrogen are essential for activity; these sites may react with the receptor. The conformations of amphetamines and indolealkylamines position their aromatic ring and alkylamino nitrogen to align with LSD's ring A and N-6. Ring A may form a π-molecular complex with the receptor, supported by a correlation between hallucinogenic activity and the energy of the highest occupied molecular orbital. The N-6 nitrogen and its sterically congruent counterparts may form an n-π* or n-σ* donor-acceptor complex. Additional groups (methoxy, hydroxyl, pyrrole ring) contribute favorable orbital energy.

Cannabis increases susceptibility to false memory

Proceedings of the National Academy of Sciences February 10, 2020 Lilian Kloft, Henry Otgaar, Arjan Blokland et al. 49 citations

Under the acute influence of THC, healthy volunteers showed a heightened tendency to form false memories compared to those given a placebo. In a double-blind, randomized trial, 64 participants completed memory tasks—including associative word lists and two virtual-reality misinformation scenarios—immediately while intoxicated and again one week later while sober. Intoxicated individuals exhibited a stronger false-recognition bias, especially when test items were weakly associated with studied material, and were more susceptible to misinformation in eyewitness and perpetrator scenarios. These false-memory effects were largely confined to the acute intoxication phase. The findings suggest that cannabis increases false-memory proneness and have practical implications for police interviews with suspects and eyewitnesses.

Molecular design of a therapeutic LSD analogue with reduced hallucinogenic potential

Proceedings of the National Academy of Sciences April 14, 2025 Jeremy R Tuck, Lee E Dunlap, Yara A Khatib et al. 32 citations

A newly designed compound, (+)-JRT, structurally similar to LSD but with reduced hallucinogenic effects, promotes the growth of dendritic spines in the cortex—a process that is diminished in neuropsychiatric diseases such as depression, addiction, and schizophrenia. In behavioral tests, (+)-JRT showed antidepressant-like and cognition-enhancing effects without worsening signs related to psychosis. This suggests that nonhallucinogenic compounds that promote neuroplasticity could be safer alternatives to psychedelics for treating conditions where psychedelics pose risks.

Phylogenomics of the psychoactive mushroom genus Psilocybe and evolution of the psilocybin biosynthetic gene cluster

Proceedings of the National Academy of Sciences January 9, 2024 Virginia Ramírez-Cruz, Giuliana Furci, Alexander J. Bradshaw et al. 30 citations

The psychedelic alkaloid psilocybin, driving Psychedelics and Drug Studies, first evolved in the mushroom genus Psilocybe around 67 million years ago. Evolutionary biology indicates its biosynthetic gene cluster transferred horizontally 4 to 5 times to other fungi between 40 and 9 million years ago. Using 71 fungal metagenomes, Phylogenetics of 2,983 gene families reveals Psilocybe's deep Biology. Two distinct psilocybin gene cluster arrangements correspond to major clades, suggesting independent acquisitions of this alkaloid's chemical synthesis, impacting Fungal Biology and Applications.

RNA synthesis in isolated brian nuclei after administration of d-lysergic acid diethylamide (LSD) in vivo.

Proceedings of the National Academy of Sciences March 1, 1975 Ian R. Brown 24 citations

Two and a half hours after rabbits received LSD intravenously, their isolated brain nuclei showed increased RNA synthesis. Transcription rose by 54% in brain stem nuclei and by 13% in cerebral hemisphere nuclei compared to saline controls. Both nucleoplasmic and nucleolar RNA synthesis were elevated. The primary activity in the assay came from nucleoplasmic RNA polymerase, as alpha-amanitin reduced synthesis by over 70% in both drug and control groups.

Chemical ecology and convergent evolution of natural hallucinogens: From ecological defense to conserved neural targets

Proceedings of the National Academy of Sciences June 24, 2026 Yibo Wang, H Wang, C T Lin et al.

Natural hallucinogenic compounds like mescaline and psilocybin evolved independently across plants, fungi, and animals through a 'building-block' biosynthetic logic that repurposes primary metabolism. These molecules likely function as defensive agents or manipulators of herbivore and pollinator behavior, not primarily for human psychoactivity. Endogenous mammalian tryptamines appear to serve cytoprotective and stress-response roles via sigma-1 receptors, not hallucinogenic functions. Across kingdoms, these compounds converge on conserved neural targets such as serotonergic systems, making human psychoactivity an evolutionary by-product of molecules selected for ecological interactions with animals sharing deeply conserved receptor architectures.

Conscious and nonconscious thought: Insights from the neuroscience of decision-making

Proceedings of the National Academy of Sciences May 26, 2026 N. Shadlen Michael

Conscious thought does not require a special neural mechanism but arises from the same representations used in nonconscious decision-making. Nonconscious thoughts are structured as interrogations that produce provisional intentions guiding action without awareness, relying on persistent neural representations that encode both potential actions and the questions giving them meaning. These states may preserve source-sensitive structure supporting minimal experiential organization. Conscious thought emerges when such a state is reformatted for potential report to another mind or oneself, recruiting theory of mind and narrative structure and placing its content in a shared space. This proposal bridges nonconscious decision mechanisms to phenomenal consciousness, placing part of the hard problem within empirical reach.